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11.
12.
Yuko Habuta Naoaki Narishige Kazu Okumura Naonobu Katada Miki Niwa 《Catalysis Today》2003,78(1-4):131-138
Vanadium oxide spread highly on TiO2 (anatase, A) and SnO2, and rather densely on TiO2 (rutile, R) and ZrO2 to make the monolayer in less than 4–5 V nm−2. Profile of acid site of the monolayer was measured by temperature programmed desorption of ammonia, and its relation with the surface oxidation state was studied. The acid site density was high on the V2O5/TiO2 (A) independent of the degree of oxidation. On the other hand, that of V2O5/TiO2 (R) and V2O5/ZrO2 depended on the oxidation state, and the high value of the concentration was observed on the oxidized one. The strength of acid site generated on the V2O5 monolayer on TiO2 was as high as on the HZSM-5 zeolite. Turnover frequency (TOF) of propane conversion, and product selectivity were measured in propane oxidation. Among tested oxides, the V2O5/TiO2 (A) showed the high TOF and selectivity to form propylene, while those loaded on TiO2 (R) and ZrO2 the small TOF and poor selectivity. Therefore, the reaction profile of activity and selectivity could be related with the extent of spreading and solid acidity. An idea of limit of the acid site density ca. 1.5 nm−2 on the monolayer was elucidated. 相似文献
13.
Masahiro Tajima Miki Niwa Yasushi Fujii Yutaka Koinuma Reiji Aizawa Satoshi Kushiyama Satoru Kobayashi Koichi Mizuno Hideo Ohuˆchi 《Applied catalysis. B, Environmental》1997,12(4):1418
The decomposition of chlorofluorocarbons (CFCs) in the presence of water was examined over a variety of solid acid catalysts. The TiO2ZrO2 catalyst was found to have the highest activity and longest life among the catalysts examined. The activity of the TiO2ZrO2 catalysts depended upon the content of TiO2. At the contents of TiO2 from 58 to 90 mole%, the TiO2ZrO2 catalysts exhibited high activity, and these catalysts were proven to contain TiZrO4 crystal. From the study of the XRD peak intensity of the TiZrO4 crystal, it was highest on the TZ-58 which contained 58 mole% of TiO2, and decreased with increasing the content of TiO2. Furthermore, the conversion of CFC113 measured at 673 K was highest at TZ-58, and decreased gradually with increasing TiO2 content. Therefore, the TiZrO4 crystal influences the activity of decomposition of CFC113. However, the TiO2ZrO2 catalyst was gradually deactivated during the reaction due to the elimination of titanium atoms. A good relationship was found between the activity on TiO2ZrO2 catalyst and bond energy of CCl in the compounds of chlorofluorocarbons and hydrochlorocarbons, suggesting that the rate controlling step was the cleavage of CCl bond. 相似文献
14.
Shigeji Taniguchi Toshio Shibata Naoyuki Asanuma Hanyi Lou Fuhui Wang Weitao Wu 《Oxidation of Metals》1993,39(5-6):457-473
The oxidation behavior of TiAl coupons coated with a fine-grain Co-30Cr-4Al (mass %) film of about 30-m thickness has been studied at 1100–1400 K in a flow of purified oxygen at atmospheric pressure for up to 500 ks. Three oxidation stages were recognized: initial transient, parabolic, and accelerated stages. However, at 1100 K a parabolic stage continues for more than 800 ks. The activation energy for parabolic oxidation agrees with reported values for the oxidation of alumina-former alloys, although the mass gains during the parabolic stages are relatively small at 1200 and 1300 K. Micropores developed mainly at the scale/coating and coating/substrate interfaces as oxidation proceeded. This is attributable to recrystallization of the coating during oxidation and a Kirkendall effect due to preferential diffusion of Co into the substrate. The accelerated oxidation can be explained in terms of the formation of rutile mounds on the scale. 相似文献
15.
The finite element polyerystal model (FEPM) was extended and applied to simulate the development of the cold rolling textures of matrix aluminum in deformation processed two-phase 10% and 20% Nb/Al(in volume fraction) metal-metal composites on the basis of slip deformation of individual grains. This simulation method can assure the continuity of stress and displacement at the boundary during heterogeneous deformation and take arbitrary boundary conditions into consideration. The starting hot-extruded textures, as initial input condition, were taken into account in the FEPM simulation. The simulation results show that the main texture components and their evolution after various cold rolling reductions in 10% and 20% Nb/Al metal-metal composites are well qualitatively in agreement with the experimental ones. The initially extruded textures are rather weak, so they have no much influence on the simulated final cold rolling textures of the matrix aluminum for Nb/Al composites. 相似文献
16.
Porous Ti compacts for biomedical applications are successfully fabricated in the porosity range from 5.0 to 37.1 vol% by controlling sintering conditions and Ti powder sizes. Young’s modulus and bending strength at the porosity of around 30 vol% are found to be similar to those of human cortical bone. 相似文献
17.
Ryu Komatsu Ryo Nakazato Takeru Sasaki Akio Suzuki Naoyuki Senda Takuya Kawata Yasuhiro Jimbo Tomoya Aoyama Naoto Ohno Susumu Kawashima Hisao Ikeda Shingo Eguchi Yoshiharu Hirakata Shunpei Yamazaki Takashi Shiraishi Seiji Yasumoto Masataka Nakada Masataka Sato Chris Bower Darryl Cotton Andrew Matthews Piers Andrew Catalin Gheorghiu Johan Bergquist 《Journal of the Society for Information Display》2015,23(2):41-49
In this study, a 5.9‐inch foldable active‐matrix organic light emitting diode (AMOLED) display was developed. A folding test was performed repeatedly. The display survived the folding test (100,000 folds) with a curvature radius of 2 mm. To protect an organic light emitting diode (OLED) against moisture, inorganic passivation layers are provided on the upper and lower sides of the flexible display. Using our transfer technology, high density passivation layers can be obtained. The measured water vapor transmission rate of the layer is 7 × 10?6 g/m2?day or less, which improves OLED reliability. With these techniques, we have developed a book‐type display, which is repeatedly foldable like a book, and a tri‐fold display including a display area, which is foldable in three. 相似文献
18.
Tetsuo Yamada Naoyuki Mizuhara Hisashi Yamamoto Masayuki Matsui 《Computers & Industrial Engineering》2009,56(3):1113-1125
For sustainable manufacturing, manufacturers should construct and design inverse manufacturing systems consisting of assembly and disassembly systems. The sorting process in the disassembly system is the first process of the whole inverse manufacturing system. Therefore, it can become a bottleneck and decrease the productivity of the whole inverse manufacturing systems.This study focuses on a disassembly system with reverse blocking in a sorting process [Yamada, T., & Matsui, M. (2003). Disassembly production systems and its design issues. Reprints of Japan Industrial Management Association, Spring meeting, Chofu, Japan, May, 144–145 (in Japanese)]. It generalizes the queuing model and discusses the performance of the disassembly system by mathematical and numerical analysis. First, the sorting process with reverse blocking is generally modeled as a queuing system. Next, the stationary state equations of the system are formulated, and the objective function is set as the throughput. Finally, the system performance is discussed by mathematical and numerical analysis in cases of a different number of stations and buffers, and also an example of the system design is shown and discussed in view of the busy rate, blocking probability and throughput. 相似文献
19.
We consider the minimum maximal matching problem, which is NP-hard (Yannakakis and Gavril (1980) [18]). Given an unweighted simple graph G=(V,E), the problem seeks to find a maximal matching of minimum cardinality. It was unknown whether there exists a non-trivial approximation algorithm whose approximation ratio is less than 2 for any simple graph. Recently, Z. Gotthilf et al. (2008) [5] presented a -approximation algorithm, where c is an arbitrary constant.In this paper, we present a -approximation algorithm based on an LP relaxation, where χ′(G) is the edge-coloring number of G. Our algorithm is the first non-trivial approximation algorithm whose approximation ratio is independent of |V|. Moreover, it is known that the minimum maximal matching problem is equivalent to the edge dominating set problem. Therefore, the edge dominating set problem is also -approximable. From edge-coloring theory, the approximation ratio of our algorithm is , where Δ(G) represents the maximum degree of G. In our algorithm, an LP formulation for the edge dominating set problem is used. Fujito and Nagamochi (2002) [4] showed the integrality gap of the LP formulation for bipartite graphs is at least . Moreover, χ′(G) is Δ(G) for bipartite graphs. Thus, as far as an approximation algorithm for the minimum maximal matching problem uses the LP formulation, we believe our result is the best possible. 相似文献
20.
Miyazawa M Zeng P Iso N Hirata T 《IEEE transactions on pattern analysis and machine intelligence》2006,28(7):1127-1134
The Euclidean distance transform is one of the fundamental operations in image processing. It has been widely used in computer vision, pattern recognition, morphological filtering, and robotics. This paper proposes a systolic algorithm that computes the Euclidean distance map of an N /spl times/ N binary image in 3N clocks on 2N/sup 2/ processing cells. The algorithm is designed so that the hardware resources are reduced; especially no multipliers are used and, thus, it facilitates VLSI implementation. 相似文献